63273-23-4Relevant academic research and scientific papers
Total synthesis of spirotryprostatin B via diastereoselective prenylation
Trost, Barry M.,Stiles, Dylan T.
, p. 2763 - 2766 (2007)
Spirotryprostatin B was synthesized in eight steps, utilizing an efficient palladium-catalyzed prenylation reaction to construct the quaternary C3 stereocenter. The decarboxylation-alkylation of a series of substituted β-keto esters is described, demonstr
The Preparation of Synthetic Analogues of Strigol
Johnson, Alan W.,Gowda, Gopala,Hassanali, Ahmed,Knox, John,Monaco, Sam,et al.
, p. 1734 - 1743 (2007/10/02)
A range of analogues of the natural germination stimulant, strigol, for parasitic weeds of the genera Striga and Orobanche, has been prepared.Most of the products contain an α-formyl-γ-lactone (or α-formyl-γ-lactam) grouping attached through an enol-ether linkage to the 5-position of a but-2-enolide.Some have shown sufficiently high activities as to warrant large-scale field trials.
