Welcome to LookChem.com Sign In|Join Free

CAS

  • or

6332-28-1

Post Buying Request

6332-28-1 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

6332-28-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6332-28-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,3 and 2 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 6332-28:
(6*6)+(5*3)+(4*3)+(3*2)+(2*2)+(1*8)=81
81 % 10 = 1
So 6332-28-1 is a valid CAS Registry Number.

6332-28-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-phenyl-N-(2-phenylethyl)ethanamine,hydrochloride

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6332-28-1 SDS

6332-28-1Downstream Products

6332-28-1Relevant articles and documents

Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism

Babón, Juan C.,Esteruelas, Miguel A.,López, Ana M.,O?ate, Enrique

supporting information, p. 2177 - 2188 (2020/06/08)

The transformation of alkyl nitriles to symmetrical and asymmetrical secondary aliphatic amines promoted by the hexahydride complex OsH6(PiPr3)2 (1) is described, and the mechanisms of the reactions involved are established. Complex 1 catalyzes the aforementioned transformations of aryl-, pyridyl-, and alkoxy-functionalized alkyl nitriles with linear or branched chains. The formation of the secondary amines involves primary imines, primary amines, and secondary imines as organic intermediates. The reactions take place under mild conditions (toluene, 100 °C, and 4 bar of H2). Stoichiometric reactions of 1 with pivalonitrile and 2-methoxyacetonitrile have allowed us to isolate the trihydride azavinylidene derivatives OsH3{═N═CHR}(PiPr3)2 (R = tBu (3), CH2OMe (4)). Their formation involves the insertion of the N-C triple bond of the substrates into an Os-H bond of the unsaturated tetrahydride OsH4(PiPr3)2 (A), which is generated by reductive elimination of H2 from the hexahydride precursor. The reaction of these trihydride azavinylidene species with H2 is the key step for the reduction of the N-C triple bond of the nitriles. In the absence of H2, the attack of A to the azavinylidene ligand produces the rupture of its C(sp2)-C(sp3) bond. As a consequence of this attack and the presence of primary imines and amines in the reaction media, the binuclear complexes (PiPr3)2H4Os(μ-CN)OsH3{κ1-N-(NH═CHCH2OMe)}(PiPr3)2 (5) and (PiPr3)2H4Os(μ-CN)OsH3{κ1-N-(NH2CH2CH2OMe)}(PiPr3)2 (6) have been isolated and characterized by X-ray diffraction analysis, for 2-methoxyacetonitrile. DFT calculations reveal noticeable similarities between the hydrogenations of nitriles to primary imines and those of primary imines to primary amines.

A study of the complexation of bis(m-phenylene) crown ethers and secondary ammonium ions

Bryant, William S.,Guzei, Ilia A.,Rheingold, Arnold L.,Merola, Joseph S.,Gibson, Harry W.

, p. 7634 - 7639 (2007/10/03)

Two macrocycles, bis(m-phenylene)-26-crown-8 (1) and bis(m-phenylene)-32-crown-10 (2), were combined with several linear components, dibenzyl- (3·PF6), di-n-butyl- (4·PFe), and diphenethyl(5·PF6) ammonium hexafluorophosphate salts. The smaller macrocycle 1 was shown not to complex effectively with any of the ammonium salts in solution by 1H NMR, but 1:1 complexes were shown to exist in the "gas phase" as [1:3], [1:4], and [1:5] by high-resolution fast atom bombardment mass spectrometry (HRFABMS) and electrospray ionization mass spectrometry (ESIMS). The X-ray crystal structure of macrocycle 1 is reported. The larger macrocycle 2 did form 1:2 complexes with the ammonium salts in solution, which were observed as well in the solid and gas phases. X-ray crystal structures of the pseudorotaxanes [2:(3)2]·2PF6 and [2:(5)2]·2PF6 were determined and are discussed. The pseudorotaxanes are stabilized by hydrogen bonding between the ammonium hydrogens of the linear salt unit and the oxygens of the crown ether macrocycle. Secondary stabilization also occurs by edge-to-face π stacking.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 6332-28-1