63327-11-7

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 79-04-9 chloroacetyl chloride 

Downstream Products

• 592529-23-2 2-(4-methylsulfanyl-phenyl)-1-{2-[2-(4-methylsulfanyl-phenyl)-2-oxo-ethyl]-pyrrolidin-1-yl}-ethanone 
• 36187-57-2 1-(4-fluorophenyl)-2-(4-(methylthio)phenyl)ethanone 
• 177560-74-6 1-phenyl-2-[4-(methylthio)phenyl]-ethan-1-one 
• 1006595-96-5 N-[3-(2-benzothiazolyl)-4,5,6,7-tetrahydro-6-methylthieno[2,3-c]pyridin-2-yl]-2-(4-methylthiophenyl)acetamide 
• 181696-80-0 1-phenyl-2-[4-(methylthio)phenyl]-ethan-1-one oxime 
• 181697-28-9 5-difluoromethyl-4-(4-methylthiophenyl)-3-phenylisoxazole 
• 181696-18-4 5-difluoromethyl-4-(4-(methylsulfonyl)phenyl)-3-phenylisoxazole 
• 143818-87-5 4-[3,3-Diethyl-1-(4-methylsulfanyl-benzylcarbamoyl)-4-oxo-azetidin-2-yloxy]-benzoic acid 
• 132470-25-8 1-(4-Fluorophenyl)-2-(4-(methylsulfonyl)phenyl)ethanone 

Relevant academic research and scientific papers

The Synthesis of Thiophenium and Oxazolium Salts from Diazoketones

4-Diazoacetylthianthren with perchloric acid in acetonitrile gave 2-oxo-1,2-dihydrothieno-thianthrenium perchlorate which gave the corresponding enol ether with diazomethane.This ether was compared with 3-methoxy-1-methylbenzothiophenium perchlorate, prepared from 3-methoxythiophen, and which was much more stable to solvolysis than the demethoxy-analogue.In contrast to the 4-diazoacetylthianthren, 7-diazoacetyl-2-methylbenzothiophen with acetonitrile and perchloric acid cyclized in an alternative mode to give a new synthesis of 2-methyl-4-substituted oxazolium perchlorates.