63327-14-0Relevant academic research and scientific papers
Ferric chloride hexahydrate-catalyzed highly regio- And stereoselective conjugate addition reaction of 2,3-allenoates with grignard reagents: An efficient synthesis of β,γ-alkenoates
Chai, Guobi,Lu, Zhan,Fu, Chunling,Ma, Shengming
supporting information; experimental part, p. 1946 - 1954 (2011/02/26)
Ferric chloride hexahydrate was shown to be an efficient catalyst for the conjugate addition of 2,3-allenoates with alkyl-, aryl-, or vinyl-Grignard reagents to synthesize polysubstituted β,γ-unsaturated alkenoates with high regio- and stereoselectivity.
Highly regioselective fluorination and iodination of alkynyl enolates
Yang, Han,Xu, Bo,Hammond, Gerald B.
supporting information; experimental part, p. 5589 - 5591 (2009/06/17)
(Chemical Equation Presented) A simple yet efficient approach to various functionalized quaternary α-alkynyl α-fluoro esters and γ-iodoallenoates from readily available allenoates through an alkynyl enolate intermediate generated by LDA is presented. Reac
Palladium-catalyzed alkylation of vinyl oxiranes with substituted allenes. Direct access to bifunctionalized allylic alcohols
Nanayakkara, Perli,Alper, Howard
, p. 4686 - 4691 (2007/10/03)
The first palladium-catalyzed alkylation of vinyl oxiranes with substituted allenes to form functionalized allylic alcohols is described. The reaction of activated allenes 5 with vinyl oxiranes 1 in the presence of catalytic amounts of Pd(PPh3)
Hypolipidemic allene carboxylic acids
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, (2008/06/13)
The compounds are 4-aryl substituted buta-2,3-dienoic acids and esters thereof which may also be lower alkyl-substituted at any of the 2- and 4-positions, e.g., 4-(p-methoxyphenyl)-2-methyl-buta-2,3-dienoic acid. The compounds are useful as pharmaceutical
