6339-91-9Relevant academic research and scientific papers
Spectral Properties of Fluorogenic Thiophene-derived Triarylmethane Dyes
Stensrud, Kenneth F.,Zanotti, Kimberly J.,Waggoner, Alan S.,Armitage, Bruce A.
, p. 406 - 410 (2018/11/27)
Spectral properties and fluorogenic behaviors of five novel thiophene variants of malachite green (MG), termed MGTs, were determined. Appreciable changes as a function of homologation and substitution pattern, including absorption band positions and inten
Efficient synthesis of Bis(4-Dimethaminophenyl)arylmethanes and Bis(4-Diamethaminophenyl)alkanes using iodine reagent
Bachhav, Harshal M.,Takale, Balaram S.,Telvekar, Vikas N.
, p. 1909 - 1914 (2013/05/21)
A novel synthetic utility of NaICl2 for the preparation of bis(4-dimethaminophenyl)arylmethanes and bis(4-dimethaminophenyl)alkanes is described. In the presence of an aqueous solution of NaICl2, the reaction of arenes with aromatic aldehydes gives corresponding triarylmethane derivatives regioselectively in moderate to good yields. The method is also useful for the preparation of diarylalkane derivatives by using aliphatic aldehydes. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications to view the free supplemental file.
SbCl3-catalyzed one-pot synthesis of 4,4′-diamino- triarylmethanes under solvent-free conditions: Synthesis, characterization, and DFT studies
Bardajee, Ghasem Rezanejade
experimental part, p. 135 - 144 (2011/05/16)
A simple, efficient, and mild procedure for a solvent-free one-step synthesis of various 4,4′-diaminotriarylmethane derivatives in the presence of antimony trichloride as catalyst is described. Triarylmethane derivatives were prepared in good to excellent yields and characterized by elemental analysis, FTIR, 1H and 13C NMR spectroscopic techniques. The structural and vibrational analysis were investigated by performing theoretical calculations at the HF and DFT levels of theory by standard 6-31Gs *, 6-31G*/B3LYP, and B3LYP/cc-pVDZ methods and good agreement was obtained between experimental and theoretical results.
Montmorillonite K10 clay catalysed Baeyer condensation of heterocyclic aldehydes with N,N-dimethylaniline: Synthesis and photo irradiation studies of heteroaryldiarylmethanes
Shanmuga,Varma
, p. 1258 - 1263 (2007/10/03)
The montmorillonitemK10 clay catalysed Baeyer condensation of a number of aromatic heterocyclic aldehydes (1-7) with N,N-dimethylaniline affords novel triarylmethanes (8-14) in good yield. The triarylmethane 8 was irradiated at 325 nm for 1 hr under different solvent systems and the photoproducts were identified as 15 and 16.
