634190-97-9

Upstream product

• 106023-51-2 phenyl (5R)-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 106-95-6 allyl bromide 
• 23661-29-2 phenyl 2,3,4,6-tetra-O-acetyl-1-seleno-β-D-glucopyranoside 
• 4981-97-9 phenyl 1-seleno-β-D-glucopyranoside 

Downstream Products

• 634190-95-7 Phosphoric acid (2R,4aR,6S,7R,8S,8aR)-8-allyloxy-2-phenyl-6-phenylselanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester diphenyl ester 

Relevant academic research and scientific papers

Highly diastereoselective radical cyclization of a glucose-derived enol ether radical cation/phosphate anion pair

Diastereomeric 3-O-allyl-4,6-O-benzylidene-2-O-(diphenylphosphatoxy) β-D-gluco- and β-D-manno-pyranosyl phenylselenides were prepared and subjected to treatment with tributyltin hydride and AIBN. The gluco-compound undergoes smooth radical cyclization to