106023-51-2

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 4981-97-9 phenyl 1-seleno-β-D-glucopyranoside 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 1666-13-3 diphenyl diselenide 
• 23661-29-2 phenyl 2,3,4,6-tetra-O-acetyl-1-seleno-β-D-glucopyranoside 

Downstream Products

• 106023-50-1 phenyl 2,3-di-O-acetyl-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 192505-47-8 phenyl 3-O-methyl-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 247152-88-1 phenyl 3-O-pivaloyl-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 634190-97-9 (2R,4aR,6S,7R,8R,8aR)-8-Allyloxy-2-phenyl-6-phenylselanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 600121-15-1 phenyl 2-O-benzyl-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 872050-77-6 Acetic acid (2S,3R,4S,5R,6R)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-hydroxy-2-phenylselanyl-4-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester 
• 872050-90-3 C₅₀H₆₆O₃₀Se 
• 872050-80-1 C₅₆H₈₀O₃₀SeSi 
• 331455-94-8 phenyl 2-O-acetyl-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-β-D-selenoglucopyranoside 
• 331455-93-7 Acetic acid (2R,4aR,6S,7R,8S,8aR)-2-phenyl-6-phenylselanyl-8-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 600121-19-5 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-1-seleno-β-D-glucal 
• 600121-14-0 phenyl 3-O-acetyl-2-O-benzyl-4,6-benzylidene-1-seleno-β-D-glucopyranoside 
• 634190-95-7 Phosphoric acid (2R,4aR,6S,7R,8S,8aR)-8-allyloxy-2-phenyl-6-phenylselanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester diphenyl ester 
• 106023-52-3 phenyl 2,3-O-isopropylidene-4,6-O-benzylidene-β-D-selenoglucopyranoside 

Relevant academic research and scientific papers

Highly diastereoselective radical cyclization of a glucose-derived enol ether radical cation/phosphate anion pair

Diastereomeric 3-O-allyl-4,6-O-benzylidene-2-O-(diphenylphosphatoxy) β-D-gluco- and β-D-manno-pyranosyl phenylselenides were prepared and subjected to treatment with tributyltin hydride and AIBN. The gluco-compound undergoes smooth radical cyclization to

Regioselective Lipase-catalysed acylation of 4,6-O-benzylidene-α- and - β-D-pyranoside derivatives displaying a range of anomeric substituents

The application of Lipase enzymes to effect regioselective C-3-O- acylation of 4,6-O-benzylidene-β-D-gluco- and -galactopyranosides displaying a range of anomeric substituents, and C-2-O-acylation of phenyl 4,6-O- benzylidene-α-D-glucopyranoside and ethyl 4,6-O-benzylidene-1-thio-α-D- glucopyranoside is reported. In particular this method has allowed introduction of a variety of acyl protecting groups at the C-3 hydroxyl group of ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 11.

Regioselective lipase-catalysed acylation of 4,6-O-benzylidene-β-D-pyranoside derivatives displaying a range of anomeric substituents

The application of lipase enzymes to effect regioselective C-3-O-acylation of 4,6-O-benzylidene-β-D-gluco- and galactopyranosides displaying a range of anomeric substituents is reported. In particular this method has allowed introduction of a variety of acyl protecting groups at the C-3 hydroxyl group of ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 9.

Electron Spin Resonance Spectroscopic Investigation of Carbohydrate Radicals. Part 2. Conformation and Configuration in Pyranos-1-yl Radicals

Carbohydrate free radicals were regiospecifically generated at C-1 of acylated and alkylated pyranosyl derivatives in non-aqueous solution and their conformations were deduced from the hyperfine splittings of their e.s.r. spectra.The preferred conformatio