63444-08-6Relevant academic research and scientific papers
Synthesis and Crystal Structure of Tetramethylammonium μ-Pentachlorothiophenolato-bis
Cooper, Mervyn K.,Duckworth, Paul A.,Saporta, Manuela
, p. 570 - 573 (1980)
The reaction of with Tl and Ag yields the title complex .The i.r. spectrum of this complex in tetrahydrofuran has distinct carbonyl-stretching bands at 2 073w, 2 062m, 1 977m (sh), 1 941vs, 1 916s, and 1 876s cm-1 which are consistent with a bent W-S-W bridge.X-Ray analysis using 2 770 diffractometer data (Mo-Kα radiation) shows that the W-S-W angle is 132.1 deg.Crystals are triclinic, space group P1, with a=13.682(3), b=11.699(2), c=10.597(2) Angstroem, α=91.71(2), β=100.31(2), γ=92.20(2) deg, and Z=2.
