Synthesis and Crystal Structure of Tetramethylammonium μ-Pentachlorothiophenolato-bis

DOI: 10.1039/DT9800000570

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 570 - 573 (1980)

Update date:2022-08-05

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Authors:

Cooper, Mervyn K.

Duckworth, Paul A.

Saporta, Manuela

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Article abstract of DOI:10.1039/DT9800000570

The reaction of with Tl and Ag yields the title complex <(CO)5W-SC6Cl5-W(CO)5>.The i.r. spectrum of this complex in tetrahydrofuran has distinct carbonyl-stretching bands at 2 073w, 2 062m, 1 977m (sh), 1 941vs, 1 916s, and 1 876s cm^-1 which are consistent with a bent W-S-W bridge.X-Ray analysis using 2 770 diffractometer data (Mo-K_α radiation) shows that the W-S-W angle is 132.1 deg.Crystals are triclinic, space group P1, with a=13.682(3), b=11.699(2), c=10.597(2) Angstroem, α=91.71(2), β=100.31(2), γ=92.20(2) deg, and Z=2.

Full text of DOI:10.1039/DT9800000570

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