634603-35-3

Basic information

• Product Name: ethyl 3-oxo-4-phenylhept-6-enoate
• Synonyms: ethyl 3-oxo-4-phenylhept-6-enoate
• CAS NO: 634603-35-3
• Molecular Weight: 246.306
• Mol File: 634603-35-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 3-oxo-4-phenylhept-6-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-oxo-4-phenylhept-6-enoate(634603-35-3)
• EPA Substance Registry System: ethyl 3-oxo-4-phenylhept-6-enoate(634603-35-3)

Safety Data

• Hazardous Substances Data: 634603-35-3(Hazardous Substances Data)

Upstream product

• 718-08-1 ethyl 3-oxo-4-phenylbutyrate 
• 106-95-6 allyl bromide 
• 30160-48-6 N-Allyl-2-phenylethanamide 
• 5558-87-2 2-phenylpent-4-enenitrile 
• 105-36-2 ethyl bromoacetate 

Downstream Products

• 634603-42-2 5-bromo-1,3-bis(phenoxymethyl)-6-(1-phenylbut-3-enyl)-1H-pyrimidine-2,4-dione 
• 634603-41-1 5-bromo-6-(1-phenylbut-3-enyl)-1H-pyrimidine-2,4-dione 
• 634603-38-6 6-(1-phenylbut-3-enyl)-1H-pyrimidine-2,4-dione 
• 634603-37-5 6-(1-phenylbut-3-enyl)-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one 

Relevant articles and documents

Thermolysis of geminal diazides: Reagent-free synthesis of 3-hydroxypyridines

An operationally simple protocol for the rapid and efficient construction of highly substituted 3-hydroxypyridines is presented. The thermally induced cyclization of easily constructed geminal diazides derived from β- ketoesters having an additional olefin moiety affords the title compounds in yields up to 97% under reagent-free conditions. The new method allows for the synthesis of preparative quantities of material. Additionally, the synthetic utility of the pyridine products for the synthesis of valuable heterocycles is described.