63479-65-2

Upstream product

• 883718-69-2 4,6-di-O-benzyl-3-O-propargyl glucal 
• 67-56-1 methanol 
• 203630-08-4 1,5-Anhydro-4,6-di-O-benzyl-2-deoxy-D-arabino-hex-1-enitol 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Relevant academic research and scientific papers

FeCl3/C as an efficient catalyst for Ferrier rearrangement of 3,4,6-tri-O-Benzyl-D-glucal

FeCl3/C was used as an efficient and convenient promoter for glycosylation through Ferrier-type rearrangement of 3,4,6-tri-O-benzyl-D-glucal, which is a relatively unreactive substrate for this type of reaction. The method was applicable to a w

Aluminium triflate catalysed O-glycosidation: Temperature-switched selective Ferrier rearrangement or direct addition with alcohols

A temperature-controlled mechanism switch between the Al(OTf) 3-catalysed direct addition of alcohols or the Ferrier rearrangement reactions in some glycals is presented. The scope and limitations are investigated as are the influence of the st

NaHSO4 supported on silica gel: An alternative catalyst for Ferrier rearrangement of glycals

NaHSO4 supported on silica gel catalyses the Ferrier rearrangement reaction of 3,4,6-tri-O-acetyl-d-glucal with alcohols and thiols to give the corresponding 2,3-unsaturated glycosides in high anomeric selectivity and good to excellent yield in short reaction time.

Direct Ferrier rearrangement on unactivated glycals catalyzed by indium(III) chloride

Anhydrous InCl3 has been shown to efficiently catalyze the Ferrier rearrangement by a direct allylic substitution of the hydroxyl group at C-3 position of glycals to afford the corresponding 2,3-unsaturated glycosides in high yields at ambient

Stereoselective synthesis of α-glucosides from 3-O-propargyl protected glucal exploiting the alkynophilicity of AuCl3

The stereoselective synthesis of 2,3-unsaturated α-d-glucosides by the SN2′ addition of diverse aglycones onto 4,6-di-O-benzyl-3-O-propargyl glucal was achieved using a catalytic quantity of AuCl3. The Au catalyzed reaction was explo