63486-66-8Relevant academic research and scientific papers
Introduction of oxygen functions into the α-position of β-diketones; part 8: Acyloxylation of copper(II) acetylacetonate with diacyl peroxides
Schank,Beck
, p. 787 - 788 (1994)
Replacement of only one hydrogen of the methylene group of 2,4-pentanedione (1) (acetylacetone) can be obtained by conversion of copper(II) acetylacetonate (2) with peroxydicarbonates 6 whereas dibenzoyl peroxide (3) (DBPO) leads to geminal disubstitution.
Reactions of copper(II) β-diketonates under free radical conditions. Preparation of highly congested β-diketones
Lloris, Maria E.,Galvez, Nicanor,Marquet, Jorge,Moreno-Manas, Marcial
, p. 8031 - 8042 (2007/10/02)
Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.
