634916-79-3

Upstream product

• 69980-52-5 2,3,4-tri-O-acetyl-L-rhamnopyranosyl bromide 
• 121194-96-5 N-benzyl-4-O-benzyl-1,5-dideoxy-1,5-imino-2,3-O-isopropylidene-D-mannitol 
• 127666-06-2 (3aS,7aS)-4-chloro-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole 
• 118464-50-9 6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-D-mannono-δ-lactam 
• 118493-81-5 (3aR,6R,7R,7aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-7-ol 
• 138913-30-1 (1R,4S,5S,6R)-3-chloro-4,5-O-isopropylidene-7-oxabicyclo[4.1.0]hept-2-ene-4,5-diol 
• 139432-85-2 (1R,2R,3R,6R)-6-Azido-4-chloro-2,3-O-isopropylidenecyclohex-4-ene-1,2,3-triol 
• 213180-71-3 (3aS,4R,5R,7aS)-5-Azido-4-benzyloxy-7-chloro-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxole 
• 634916-74-8 (4S,5S)-5-[(1R,2R)-2-Azido-1-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Chemoenzymatic syntheses of (-)-1-deoxymannojirimycin (DMJ) and its naturally occurring 6-O-alpha-L-rhamnopyranosyl glycoside.

The naturally occurring sugar mimetic alkaloids 1-deoxymannojirimycin (DMJ, 1) and 6-O-alpha-L-rhamnopyranosyl-DMJ (2) have each been prepared in a completely stereoselective manner from the cis-1,2-dihydrocatechol 3, itself obtained in enantiomerically p