121194-96-5

Upstream product

• 100-39-0 benzyl bromide 
• 634916-74-8 (4S,5S)-5-[(1R,2R)-2-Azido-1-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid methyl ester 
• 213180-71-3 (3aS,4R,5R,7aS)-5-Azido-4-benzyloxy-7-chloro-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxole 
• 139559-62-9 (1S,2S,3S,4S)-4,6-Dichloro-2,3-O-isopropylidenecyclohex-4-ene-1,2,3-triol 
• 139432-85-2 (1R,2R,3R,6R)-6-Azido-4-chloro-2,3-O-isopropylidenecyclohex-4-ene-1,2,3-triol 
• 138913-30-1 (1R,4S,5S,6R)-3-chloro-4,5-O-isopropylidene-7-oxabicyclo[4.1.0]hept-2-ene-4,5-diol 
• 118493-81-5 (3aR,6R,7R,7aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-7-ol 
• 118464-50-9 6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-D-mannono-δ-lactam 
• 127666-06-2 (3aS,7aS)-4-chloro-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole 
• 121194-93-2 N-benzyl-4-O-benzyl-6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-D-mannono-δ-lactam 

Downstream Products

• 121194-99-8 (3aR,6S,7R,7aR)-5-Benzyl-7-benzyloxy-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carbaldehyde 
• 634916-79-3 Acetic acid (2R,3R,4R,5S,6S)-4,5-diacetoxy-2-((3aR,6R,7R,7aR)-5-benzyl-7-benzyloxy-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-6-ylmethoxy)-6-methyl-tetrahydro-pyran-3-yl ester 
• 107244-34-8 6-epi-castanospermine 
• 121195-01-5 N-benzyl-4-O-benzyl-1,5,7,8-tetradeoxy-1,5-imino-2,3-O-isopropylidene-DL-glycero-D-manno-oct-7-enitol 
• 121250-66-6 N-benzyl-4-O-benzyl-6-O-tert-butyldimethylsilyl-1,5,7-trideoxy-1,5-imino-2,3-O-isopropylidene-L-glycero-D-manno-octitol 
• 121194-97-6 N-benzyl-4-O-benzyl-6-O-tert-butyldimethylsilyl-1,5,7-trideoxy-1,5-imino-2,3-O-isopropylidene-D-glycero-D-manno-octitol 
• 121195-00-4 N-benzyl-4-O-benzyl-6-O-tert-butyldimethylsilyl-1,5,7,8-tetradeoxy-1,5-imino-2,3-O-isopropylidene-DL-glycero-D-manno-oct-7-enitol 
• 121194-98-7 (3aR,8R,8aS,9R,9aR)-9-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-[1,3]dioxolo[4,5-f]indolizine 
• 121194-98-7 (3aR,8S,8aS,9R,9aR)-9-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-[1,3]dioxolo[4,5-f]indolizine 
• 121194-95-4 Methanesulfonate(3aR,8R,8aS,9R,9aR)-5-benzyl-9-benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-[1,3]dioxolo[4,5-f]indolizin-5-ium; 
• 121194-95-4 Methanesulfonate(3aR,8S,8aS,9R,9aR)-5-benzyl-9-benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-[1,3]dioxolo[4,5-f]indolizin-5-ium; 

Relevant academic research and scientific papers

Chemoenzymatic syntheses of (-)-1-deoxymannojirimycin (DMJ) and its naturally occurring 6-O-alpha-L-rhamnopyranosyl glycoside.

The naturally occurring sugar mimetic alkaloids 1-deoxymannojirimycin (DMJ, 1) and 6-O-alpha-L-rhamnopyranosyl-DMJ (2) have each been prepared in a completely stereoselective manner from the cis-1,2-dihydrocatechol 3, itself obtained in enantiomerically p

Synthesis of the enantiomers of 6-epicastanospermine and 1,6-diepicastanospermine from D- and L-gulonolactone.

The synthesis of the enantiomers of 6-epicastanospermine and of 1,6-diepicastanospermine from the enantiomeric gulonolactones is reported and the structure of the former is established as (1S,6R,7R,8R,8aR)-1,6,7,8-tetrahydroxyoctahydroindolizine. The inhibitory activities of the diastereomers against the amyloglucosidase-catalysed hydrolysis of p-nitrophenyl alpha-D-glucopyranoside were investigated, and the effects of 6-epicastanospermine and of 1,6-diepicastanospermine on 14 human liver glycosidases are reported.

SYNTHESIS OF 6-EPICASTANOSPERMINE AND 1,6-DIEPICASTANOSPERMINE FROM L-GULONOLACTONE AND SYNTHESIS OF L-6-EPICASTANOSPERMINE AND L-1,6-DIEPICASTANOSPERMINE FROM D-GULONOLACTONE.

The syntheses of the natural product 6-epicastanospermine , isolated from Castanospermum australe, and of 1,6-diepicastanospermine -1,6,7,8-tetrahydroxyoctahydroindolizine> from