635704-51-7Relevant articles and documents
Synthesis and reactivity of photochromic 2H-chromenes based on 3-carboxylated coumarins
Cerqueira, Nuno M. F. S. A.,Rodrigues, Ligia M.,Oliveira-Campos, Ana M. F.,Melo de Carvalho, Luis H.,Coelho, Paulo J.,Dubest, Roger,Aubard, Jean,Samat, Andre,Guglielmetti, Robert
, p. 3244 - 3253 (2007/10/03)
New photochromic 2H-chromenes (=2H-1-benzopyrans) including a 3-carboxylated coumarin nucleus were synthesized from hydroxycoumarins, and, in one case, the corresponding trimethoxysilylcarboxamide was prepared. The photochromic behavior was studied under flash-photolysis conditions. The introduction of electron-withdrawing substituents in this position of the coumarin nucleus led to a global and significant bathochromic shift in the spectra of the open forms and to an interesting intensification in the colorability.