635751-93-8

Upstream product

• 106-95-6 allyl bromide 
• 635752-00-0 3-(3,5-dimethylphenyl)-2-propyn-1-ol 

Downstream Products

• 635751-96-1 2-(3,5-dimethylphenyl)-7-oxabicyclo[3.3.0]oct-1-en-3-one 
• 1342795-42-9 (Z)-3-(3,5-dimethylbenzylidene)-4-methyltetrahydrofuran 
• 873876-65-4 6-(3,5-dimethylphenyl)-3a,4-dihydro-1H,3H-cyclopenta[c]furan-5-one 

Relevant academic research and scientific papers

Rh(I)-Catalyzed Asymmetric Intramolecular Pauson-Khand Reaction in Aqueous Media

The first rhodium-BINAP complex-catalyzed enantioselective Pauson-Khand reaction in aqueous media, which is accelerated by surfactant, is reported. The chiral rhodium catalyst is easily prepared in situ from 1 equivalent of [Rh(cod)Cl]2 and 2 e

Iron-catalyzed reductive cyclization of 1,6-enynes

A precatalyst of FeCl2 and iminopyridine was activated in situ by a combination of diethylzinc and magnesium bromide etherate; it catalyzed the reductive cyclization of 1,6-enynes to give pyrrolidine and tetrahydrofuran derivatives from N-and O

Microwave-assisted rhodium-complex-catalyzed cascade decarbonylation and asymmetric Pauson-Khand-type cyclizations

Microwave-assisted Rh-diphosphane-complex-catalyzed dual catalysis is reported. This cooperative process provides [2+2+1] cycloadducts by sequential decarbonylation of aldehyde or formate and carbonylation of enynes within a short period of time. Various