6361-19-9Relevant academic research and scientific papers
Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols
Hoover, Jessica M.,Stahl, Shannon S.
supporting information; experimental part, p. 16901 - 16910 (2011/12/04)
Aerobic oxidation reactions have been the focus of considerable attention, but their use in mainstream organic chemistry has been constrained by limitations in their synthetic scope and by practical factors, such as the use of pure O2 as the oxidant or complex catalyst synthesis. Here, we report a new (bpy)CuI/TEMPO catalyst system that enables efficient and selective aerobic oxidation of a broad range of primary alcohols, including allylic, benzylic, and aliphatic derivatives, to the corresponding aldehydes using readily available reagents, at room temperature with ambient air as the oxidant. The catalyst system is compatible with a wide range of functional groups and the high selectivity for 1° alcohols enables selective oxidation of diols that lack protecting groups.
Solvent-free oxidation of alcohols with potassium persulphate in the presence of bronsted acidic ionic liquids
Chaskar,Bhandari,Patil,Sharma,Mayeker
experimental part, p. 366 - 370 (2009/04/07)
An efficient conversion of alcohols to aldehydes was achieved using potassium persulphate and 3-methylimidazolinium methane sulfonate. Copyright Taylor & Francis Group, LLC.
Preparation of 3-(3,4,5,6-tetrahydro-phthalimido)-benzaldehydes
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, (2008/06/13)
3-(3,4,5,6-Tetrahydrophthalimido)-benzaldehydes of the type I STR1 or corresponding derivatives substituted in the phenyl ring are prepared by (a) acetalization of a 3-nitrobenzaldehyde III or of a corresponding derivative with an alcohol IV in the presen
