636596-82-2

Basic information

• Product Name: (4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsilyloxy)-3'-hydroxyoctadecanyl]-2-phenyl-1,3-dioxolane
• Synonyms: (4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsilyloxy)-3'-hydroxyoctadecanyl]-2-phenyl-1,3-dioxolane
• CAS NO: 636596-82-2
• Molecular Weight: 520.869
• Mol File: 636596-82-2.mol

Chemical Properties

• CAS DataBase Reference: (4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsilyloxy)-3'-hydroxyoctadecanyl]-2-phenyl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsilyloxy)-3'-hydroxyoctadecanyl]-2-phenyl-1,3-dioxolane(636596-82-2)
• EPA Substance Registry System: (4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsilyloxy)-3'-hydroxyoctadecanyl]-2-phenyl-1,3-dioxolane(636596-82-2)

Safety Data

• Hazardous Substances Data: 636596-82-2(Hazardous Substances Data)

Upstream product

• 460745-04-4 (2RS,4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsiloxy)-3'-hydroxy-1'-hexadecynyl]-2-phenyl-1,3-dioxolane 

Downstream Products

• 636596-83-3 (4S)-4-[(3'S,4'R)-4'-(tert-butyldimethylsilyloxy)-3'-(p-toluenesulfonyloxy)octadecanyl]-2-phenyl-1,3-dioxolane 

Relevant articles and documents

Highly stereoselective and stereodivergent synthesis of four types of THF cores in acetogenins using a C4-chiral building block

(Formula Presented) Four stereoisomers of the THF cores, synthetic intermediates of acetogenins, have been synthesized with high diastereoselectivity by asymmetric alkynylation and subsequent stereodivergent THF ring formation. The asymmetric alkynylation

Systematic Construction of a Monotetrahydrofuran-Ring Library in Annonaceous Acetogenins by Asymmetric Alkynylation and Stereodivergent Tetrahydrofuran-Ring Formation

All eight diastereoisomers of the monotetrahydrofuran-ring cores of annonaceous acetogenins have been synthesized through utilization of asymmetric alkynylation and stereodivergent one-pot tetrahydrofuran-ring formation. In all cases, the asymmetric alkyn