636603-06-0Relevant articles and documents
Asymmetric Total Synthesis of Pseudoplexaurol and 14-Deoxycrassin, two Antitumor Marine Cembrane Diterpenoids
Liu, Zuosheng,Peng, Lizeng,Li, Weidong Z.,Li, Yulin
, p. 1977 - 1980 (2003)
The first asymmetric total synthesis of two naturally occurring antitumor pseudoplexaurol and 14-deoxycrassin were achieved via two convergent synthetic sequences featured a chiral pool protocol to implement C-1 stereogenic center and Ti(0)-mediated cyclization leading to cembrane ring.