636603-74-2

Upstream product

• 171020-83-0 (1R,2S,6R,7S)-1,10,10-Trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]dec-4-ene 5-oxide 
• 636603-69-5 (2S,3S,3aS,4aS,5R,8S,8aR)-3-nitro-2-phenyl-3,5,10,10-tetramethyl-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole 

Downstream Products

• 94199-26-5 (2S,3R)-methyl 3-hydroxy-2-methyl-3-phenylpropionate 
• 116126-02-4 (+)-(2S,3R)-3-hydroxy-2-methyl-3-phenylpropanoic acid 
• 439858-53-4 (2S,3R)-3-Hydroxy-2-methyl-3-phenyl-propionaldehyde 

Relevant academic research and scientific papers

[2+3] Cycloadditions between nitroalkenes and camphor-derived oxazoline N-oxides and radical denitration of the adducts

[2+3] Cycloadditions between camphor-derived oxazoline N-oxide 2 and nitroalkenes 3a-f afforded stereoselectively adducts 4a-f. Radical denitration followed by acidic hydrolysis gave rise to anti-aldols 8a,b. The radical intermediate was also trapped by a suitable alkene, giving rise to a single stereoisomer.