637-31-0

Basic information

• Product Name: BINDSCHEDLER'S GREEN
• Synonyms: BIS(4-DIMETHYLAMINOPHENYL)AMINE;N,N,N',N'-TETRAMETHYLDIAMINODIPHENYLAMINE;Bindschedler;4-[[4-(Dimethylamino)phenyl]amino]-N,N-dimethylaniline;C.I.76125;Bis(4-dimethylaminophenyl)amide;Leuco Bindschedler's;Bis(4-dimethylaminophenyl)amine Leuco Bindschedler's Green N,N,N',N'-Tetramethyldiaminodiphenylamine
• CAS NO: 637-31-0
• Molecular Formula: C₁₆H₂₁N₃
• Molecular Weight: 255.36
• Mol File: 637-31-0.mol
• Article Data: 4

Chemical Properties

• Melting Point: 121°C
• Boiling Point: 416.7±30.0 °C(Predicted)
• Appearance: /
• Density: 1.103±0.06 g/cm3(Predicted)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 7.45±0.24(Predicted)
• CAS DataBase Reference: BINDSCHEDLER'S GREEN(CAS DataBase Reference)
• NIST Chemistry Reference: BINDSCHEDLER'S GREEN(637-31-0)
• EPA Substance Registry System: BINDSCHEDLER'S GREEN(637-31-0)

Safety Data

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 637-31-0(Hazardous Substances Data)

Usage

General Description

Bindschedler's green is a synthetic dye that is commonly used in histology and cytology to stain and visualize plant cell walls. It is a basic fuchsin derivative and appears as a green powder. When used in staining, it binds to cellulose and lignin components in the cell wall, allowing for clear visualization and differentiation of the different types of plant tissues. In addition to its use in histology, Bindschedler's green has also been employed in other applications, such as in the detection of lipid peroxidation in cells and tissues.

Upstream product

• 60-29-7 diethyl ether 
• 7732-18-5 water 
• 1990-18-7 tetrakis-(4-dimethylamino-phenyl)-hydrazine 
• 64-17-5 ethanol 
• 807306-71-4 3,7-bis(dimethylamine)phenothiazonium 
• 4486-05-9 Bindschedler's Green 
• 7647-01-0 hydrogenchloride 
• 861572-35-2 bis-(4-dimethylamino-phenyl)-trityl-amine 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 99-98-9 4-amino-N,N-dimethylaniline 
• 20491-92-3 2,4,6-trimethoxyphenol 
• 2316-27-0 C₁₆H₂₂N₃ 
• 109-72-8 n-butyllithium 
• 100-23-2 N,N-Dimethyl-4-nitroaniline 

Downstream Products

• 2877-78-3 [1,4]benzoquinone-(4-dimethylamino-phenylimine)-methylimine 
• 13916-80-8 Bis-<4-dimethylamino-phenyl>-nitrosamin 
• 2150-58-5 phenol blue 
• 1990-18-7 tetrakis-(4-dimethylamino-phenyl)-hydrazine 
• 861572-35-2 bis-(4-dimethylamino-phenyl)-trityl-amine 
• 4486-05-9 Bindschedler's Green 
• 64634-56-6 C₂₂H₂₄FN₃ 
• 55087-74-6 4,4’-bis(dimethylamino)triphenylamine 
• 67699-14-3 3-[4-(dimethylamino)phenyl]-3-[N-(4-dimethylaminophenyl)-N-(4-dimethylamino)phenylamino]phthalide 
• 67699-29-0 6-dimethylamino-3-[4-(dimethylamino)phenyl]-3-[N-(4-dimethylaminophenyl)-N-(4-dimethylamino)phenylamino]phthalide 
• 55586-94-2 3-[4-(diethylamino)-2-methylbenzoyl]-2-pyridinecarboxylic acid 
• 78496-05-6 7-[4-(diethylamino)-2-methylphenyl]-7-{bis[4-(dimethylamino)phenyl]amino}furo[3,4-b]pyridine-5(7H)-one 
• 1135975-55-1 N-(2,6-diisopropylphenyl)-1,6-diphenylthio-9-di(p-dimethylaminophenyl)-aminoperylene-3,4-dicarboximide 
• 1135975-57-3 N-(2,6-diisopropylphenyl)-1,6-di(pyridine-4-thio)-9-di(p-dimethylaminophenyl)-aminoperylene-3,4-dicarboximide 

Relevant articles and documents

Incorporation of ring nitrogens into diphenylamine antioxidants: Striking a balance between reactivity and stability

The incorporation of nitrogen atoms into the aryl rings of conventional diphenylamine antioxidants enables the preparation of readily accessible, air-stable analogues, several of which have temperature-independent radical-trapping activities up to 200-fold greater than those of typical commercial diphenylamines. Amazingly, the nitrogen atoms raise the oxidation potentials of the amines without greatly changing their radical-trapping (H-atom transfer) reactivity.

Preparation of diarylamines by the addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes

The addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes in THF (-78°C) affords the corresponding diarylamines in one-pot and the reaction appears to be general in scope. A 'nitroso'-based mechanism is proposed for this novel nitroreductive N-arylation reaction.