6374-26-1

Basic information

• Product Name: Diethyl phosphor(isothiocyanatidate)
• Synonyms: Diethyl phosphor(isothiocyanatidate)
• CAS NO: 6374-26-1
• Molecular Formula: C₅H₁₀NO₃PS
• Molecular Weight: 195.18
• Mol File: 6374-26-1.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Diethyl phosphor(isothiocyanatidate)(CAS DataBase Reference)
• NIST Chemistry Reference: Diethyl phosphor(isothiocyanatidate)(6374-26-1)
• EPA Substance Registry System: Diethyl phosphor(isothiocyanatidate)(6374-26-1)

Safety Data

• Hazardous Substances Data: 6374-26-1(Hazardous Substances Data)

Upstream product

• 505-14-6 thiocyanogen 
• 762-04-9 phosphonic acid diethyl ester 
• 598-02-7 Diethyl phosphate 
• 592-87-0 lead(II) thiocyanate 
• 2290-65-5 trimethylsilyl isothiocyanate 
• 814-49-3 diethyl chlorophosphate 
• 89430-21-7 Phosphoric acid benzo[1,3,2]dioxaphosphol-2-yl ester diethyl ester 
• 540-72-7 sodium thiocyanide 
• 89430-18-2 Phosphoric acid 2,2-diisothiocyanato-1,3-dioxa-2λ⁵-phospha-indan-2-yl ester diethyl ester 
• 1147550-11-5 ammonium thiocyanate 
• 89430-31-9 C₁₁H₁₄NO₆P₂S⁽¹⁺⁾*CNS^(1-) 
• 4972-37-6 methanesulfonic phosphoric anhydride, diethyl ester 
• 2901-90-8 bis(diethoxyphosphoryl)disulphide 
• 151-50-8 potassium cyanide 

Downstream Products

• 108753-09-9 cyclohexylthiocarbamoyl-amidophosphoric acid diethyl ester 
• 65088-78-0 N²-(diethoxyphosphinyl)-N¹-phenylthiourea 
• 58100-68-8 o-Phenylen-di(thiocarbamoyl)diphosphorsaeureamid-tetraethylester 
• 108629-76-1 (2-mercapto-phenylthiocarbamoyl)-amidophosphoric acid diethyl ester 
• 108629-77-2 (3-hydroxy-phenylthiocarbamoyl)-amidophosphoric acid diethyl ester 
• 542-90-5 ethyl isothiocyanate 
• 4697-37-4 ethyl metaphosphate 
• 110378-14-8 o-tolylthiocarbamoyl-amidophosphoric acid diethyl ester 
• 109405-29-0 benzylthiocarbamoyl-amidophosphoric acid diethyl ester 
• 2995-40-6 (4-fluoro-phenylthiocarbamoyl)-amidophosphoric acid diethyl ester 
• 54529-72-5 (morpholin-4-yl-thiocarbamoyl)-phosphoramidic acid diethyl ester 
• 66608-31-9 4-Methyl-N,N'-bis-(N-diethoxyphosphoryl-thiocarbamoyl)-1,2-phenylendiamin 
• 66608-44-4 4,5-Dimethyl-N,N'-bis-(N-diethoxyphosphoryl-thiocarbamoyl)-1,2-phenylendiamin 
• 66608-26-2 4-Chlor-N,N'-bis-(N-diethoxyphosphoryl-thiocarbamoyl)-1,2-phenylendiamin 

Relevant articles and documents

Microwave-assisted solvent-free synthesis of pseudohalophosphates

A rapid, efficient, solvent-free, and catalyst-free procedure has been developed for the synthesis of pseudohalophosphates from phosphorochloridate and sodium (or potassium) pseudohalides under microwave irradiation. Diethyl, diisobutyl, and diphenyl phosphorazidates, phosphorocyanidates, and phosphor(isothiocyanidate)s 2a-2i were prepared in good yields under mild conditions. Copyright

Pseudohalogenation of phosphites

A new type of Atherton-Todd reaction for a convenient pseudohalogenation of phosphites has been developed. Direct azidation, cyanation, and thiocyanation of (RO)2P(O)H (R = Et, i-Bu, Ph) were accomplished readily with sodium pseudohalides in acetonitrile under mild modified Atherton-Todd conditions. The corresponding phosphorochloridates were demonstrated by GC/MS to be the intermediates. Pseudohalogenations of ethyl phenylphosphinate and diphenylphosphine oxide were also investigated.

NEW APPROACH TO THE SYNTHESIS OF PHOSPHORUS ISOTHIOCYANATES

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