63753-50-4

Upstream product

• 23451-73-2 1-(4-tolythio)-3-buten-2-ol 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 107-02-8 acrolein 
• 930-22-3 epoxybutene 
• 106-45-6 para-thiocresol 

Downstream Products

• 73766-37-7 (R)-p-Tolyl-<2-(trimethylsilyloxy)-3-butenyl>-sulfoxid 
• 73766-36-6 (E)-(+)-(R)-1-(p-tolylsulfinyl)-1,3-butadiene 
• 73766-31-1 (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid 
• 73766-34-4 (+)-(R)-(2-Acetoxy-3-butenyl)-p-tolyl-sulfoxid 

Relevant academic research and scientific papers

A visible-light-induced thiol addition/aerobic oxidation cascade reaction of epoxides and thiols for the synthesis of β-hydroxylsulfoxides

A photochemical thiol addition/aerobic oxidation cascade reaction has been developed. This protocol enables efficient oxidative coupling of epoxides and thiols to access structurally valuable β-hydroxylsulfoxides. A broad range of functional groups are co

A novel rapid sulfoxidation of sulfides with cyclohexylidenebishydroperoxide

Cyclohexylidenebishydroperoxide was successfully used as the oxygen source for the oxidation of sulfides to sulfoxides for the first time. The sulfoxides were obtained in good to high yields without any detectable over-oxidation to sulfones under normal conditions.

Stereoselective Synthesis of Alcohols, II Stereochemistry of the Sigmatropic Rearrangement of 3-Substituted 2-Alkenyl Sulfoxides

Rearrangement of the 3-E-substituted allyl sulfoxides 5 to the allyl alcohols 19 and 30 proceeds with low enantiomeric selectivity.In contrast, the 3-Z-substituted allyl sulfoxide 7b rearranged uniformly via the endo-transition state 26.