637740-33-1

Basic information

• Product Name: trichloro(4-(4-carboxyphenyl)-2,2':6,2''-terpyridine)ruthenium(III)
• Synonyms: trichloro(4-(4-carboxyphenyl)-2,2':6,2''-terpyridine)ruthenium(III)
• CAS NO: 637740-33-1
• Molecular Weight: 560.809
• Mol File: 637740-33-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: trichloro(4-(4-carboxyphenyl)-2,2':6,2''-terpyridine)ruthenium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: trichloro(4-(4-carboxyphenyl)-2,2':6,2''-terpyridine)ruthenium(III)(637740-33-1)
• EPA Substance Registry System: trichloro(4-(4-carboxyphenyl)-2,2':6,2''-terpyridine)ruthenium(III)(637740-33-1)

Safety Data

• Hazardous Substances Data: 637740-33-1(Hazardous Substances Data)

Upstream product

• 158014-74-5 4'-(4-carboxyphenyl)-6,2':6',2''-terpyridine 
• 14898-67-0 ruthenium(III) chloride trihydrate 

Downstream Products

• 1352132-21-8 chloro(2,2'-bipyridine)(4-(4-carboxyphenyl)-2,2':6,2''-terpyridine)ruthenium(II) tetrafluoroborate 
• 1352132-23-0 4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine(1,10-phenanthroline)chloride ruthenium(II) tetrafluoroborate 

Relevant articles and documents

Efficient light activation of a [Ru(bpy)(tpy)Cl]+ catalyst by a porphyrin photosensitizer at small driving force

Light activation of dyads containing porphyrins and a catalytic ruthenium complex having a high oxidation potential (~1 V vs SCE) is investigated by time-resolved spectroscopy. It is shown that activation of the ruthenium complex occurs through oxidative quenching of the chromophore in the presence of a reversible electron acceptor. Despite the lack of driving force for intramolecular electron transfer, an efficient intramolecular oxidation of the catalyst is observed, suggesting that porphyrins are attractive chromophores to activate oxidation catalysts throughout the visible spectrum.

Synthesis and characterization of extended bis(terpyridine)ruthenium amino acids

(Oligopyridine)ruthenium(II) complexes have been widely used in dye sensitized solar cells and other sophisticated optical devices due to their outstanding photophysical properties and their chemical stability. Herein, we describe the longitudinal extensi