63779-63-5Relevant academic research and scientific papers
Iridium-catalyzed enantioselective allyl-alkene coupling
Hamilton, James Y.,Sarlah, David,Carreira, Erick M.
supporting information, p. 3006 - 3009 (2014/03/21)
The direct Ir-catalyzed cross-coupling between branched, racemic allylic alcohols and simple olefins is described. This transformation is catalyzed by an Ir-(P,olefin) complex and proceeds with high site selectivity and excellent enantioselectivity. The m
Substitution effects on regioselective cyclizations of 1,5- and 2,4-diphenyl-1,5-hexadiene cation radicals generated by the electron-transfer photosensitizations
Ikeda,Oikawa,Miyashi
, p. 2323 - 2326 (2007/10/02)
The 9,10-dicyanoanthracene (DCA)-sensitized electron-transfer photoreactions of E- and Z-1,5-diphenyl-1,5-hexadienes (E-2 and Z-2) gave a mixture of endo- and exo-1,5-diphenylbicyclo [2.1.1]hexanes (endo-3 and exo-3) while 2,4-diphenyl-1,5-hexadiene (1) underwent the Cope rearrangements to E-2, showing significant substitution effects on cyclization of 1,5-hexadiene cation radicals.
