638188-75-7

Upstream product

• 638188-73-5 (2S)-1-(2-((2S,4S)-5-(tert-butyldiphenylsilyloxy)-4-methylpentan-2-yl)-6-methoxy-5-(methoxymethoxy)-7-methylbenzofuran-4-yl)-2-((4R,5S,6R)-2,2,5-trimethyl-6-((S)-3-methylpent-4-enyl)-1,3-dioxan-4-yl)propan-1-ol 
• 638188-67-7 (3S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-1-(4-methoxy-2,5-bis-methoxymethoxy-3-methyl-phenyl)-3,5-dimethyl-hexan-2-ol 
• 638188-69-9 tert-Butyl-[(2S,4S)-4-(6-methoxy-5-methoxymethoxy-7-methyl-benzofuran-2-yl)-2-methyl-pentyloxy]-diphenyl-silane 
• 638188-68-8 2-[(1S,3S)-4-(tert-Butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-6-methoxy-7-methyl-benzofuran-5-ol 
• 638188-62-2 tert-Butyl-((2S,4S)-2-methyl-4-oxiranyl-pentyloxy)-diphenyl-silane 
• 638188-59-7 (2S,4S)-5-((tert-butyldiphenylsilyl)oxy)-2,4-dimethylpentan-1-ol 
• 638188-55-3 (R)-2-[(4S,5S,6R)-2,2,5-Trimethyl-6-((S)-3-methyl-pent-4-enyl)-[1,3]dioxan-4-yl]-propionic acid methyl ester 
• 638188-66-6 C₁₂H₁₇BrMgO₅ 
• 638188-56-4 (S)-2-[(4R,5S,6R)-2,2,5-Trimethyl-6-((S)-3-methyl-pent-4-enyl)-[1,3]dioxan-4-yl]-propan-1-ol 
• 638188-57-5 (R)-2-[(4S,5S,6R)-2,2,5-Trimethyl-6-((S)-3-methyl-pent-4-enyl)-[1,3]dioxan-4-yl]-propionaldehyde 
• 761457-29-8 1-bromo-4-methoxy-2,5-bis(methoxymethoxy)-3-methylbenzene 
• 777858-58-9 2-methoxy-1,4-bis(methoxymethoxy)-3-methylbenzene 
• 320742-72-1 (2S,4S)-2,4-dimethyl-1-(tert-butyldiphenylsilyloxy)-5-hexene 
• 91751-24-5 (R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal 

Relevant academic research and scientific papers

A Novel Approach toward the Synthesis of Kendomycin: Selective Synthesis of a C-Aryl Glycoside as a Single Atropisomer

(Matrix presented) A convergent and concise route to an advanced precursor 2b of kendomycin (1) has been developed by applying a SN1 ring cyclization as a key step. The resulting C-aryl glycoside was initially isolated as a rotameric mixture, b