777858-58-9Relevant academic research and scientific papers
Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides
Wang, Yi-Feng,Lonca, Geoffroy Herve,Le Runigo, Maiwenn,Chiba, Shunsuke
, p. 4272 - 4275 (2014/10/15)
Radical perfluoroalkylation of α-(biaryl-2-yl)vinyl azides is capable of supplying polyfluoroalkyl aza-polycyclic aromatic hydrocarbons (aza-PAHs). Commercially available Me3SiRf (Rf = CF 3, C2F5
A short access to the skeleton of elisabethin a and formal syntheses of elisapterosin B and colombiasin A
Preindl, Johannes,Leitner, Christian,Baldauf, Simon,Mulzer, Johann
, p. 4276 - 4279 (2014/11/08)
A short stereoselective synthesis of the Elisabethin A skeleton 4 is described, which opens a formal access to the diterpenes Elisapterosin B and Colombiasin A as well. Key reactions were an intermolecular endo-selective Diels-Alder reaction to generate t
A Novel Approach toward the Synthesis of Kendomycin: Selective Synthesis of a C-Aryl Glycoside as a Single Atropisomer
Pichlmair, Stefan,Marques, Maria M. B.,Green, Martin P.,Martin, Harry J.,Mulzer, Johann
, p. 4657 - 4659 (2007/10/03)
(Matrix presented) A convergent and concise route to an advanced precursor 2b of kendomycin (1) has been developed by applying a SN1 ring cyclization as a key step. The resulting C-aryl glycoside was initially isolated as a rotameric mixture, b
