63863-45-6Relevant academic research and scientific papers
Cyclization processes in pyrolysis of perfluorooxaalkanedicarboxylic acid derivatives
Lebedev,Berenblit,Starobin
, p. 95 - 99 (2008/09/17)
Formation of cyclic structures under the conditions of pyrolytic decarboxylation of perfluorooxaalkanedicarboxylic acids was studied.
Process for producing perfluorovinylcarboxylic acid ester
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Page 5, (2010/02/10)
The present invention relates to a method for producing a perfluorovinylcarboxylic acid ester by reacting a perfluorovinylcarboxylic acid salt with an alkylating agent. The present invention provides a method to produce perfluorovinylcarboxylic acid ester, which is used as a raw material of an ion-exchange membrane for the chloro alkali process, in high yield from starting material, a compound which can be easily produced, in a simple manner.
Process for producing fluorinated vinyl ether
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Page 6, (2008/06/13)
There is provided a process for producing a fluorinated vinyl ether from a fluorinated acid fluoride compound having an ester group as a precursor of a carboxylic acid group, or a SO2F group as a precursor of a sulfonic acid group, in high yield by simple operations. Said process is a production process comprising pyrolyzing a carboxylic acid potassium salt with a specific structure represented by the following formula in the absence of a solvent and/or while maintaining the salt in the solid state: wherein X is —CO2R or —SO2F, and R is an alkyl group.
Synthesis of perfluorinated vinyl ethers having ester group
Yamabe, Masaaki,Munekata, Seiji,Kaneko, Isamu,Ukihashi, Hiroshi
, p. 65 - 68 (2007/10/03)
A new efficient and convenient synthetic process of perfluorinated vinyl ethers containing an ester group was developed by pyrolysis in the presence of α-trifluoromethyl moiety without loss of -COF functional group followed by alcoholysis in high yield.
