63883-84-1Relevant academic research and scientific papers
Nickel-catalyzed coupling of alkenes, aldehydes, and silyl triflates
Ng, Sze-Sze,Ho, Chun-Yu,Jamison, Timothy F.
, p. 11513 - 11528 (2007/10/03)
A full account of two recently developed nickel-catalyzed coupling reactions of alkenes, aldehydes, and silyl triflates is presented. These reactions provide either allylic alcohol or homoallylic alcohol derivatives selectively, depending on the ligand em
Nickel-catalyzed, carbonyl-ene-type reactions: Selective for alpha olefins and more efficient with electron-rich aldehydes
Ho, Chun-Yu,Ng, Sze-Sze,Jamison, Timothy F.
, p. 5362 - 5363 (2007/10/03)
Described are several classes of unusual or unprecedented carbonyl-ene-type reactions, including those between alpha olefins and aromatic aldehydes. Catalyzed by nickel, these processes complement existing Lewis acid-catalyzed methods in several respects.
