639067-85-9Relevant academic research and scientific papers
Chemo-enzymatic preparations of (R)- and (S)-3-iodocyclohex-2-en-1-yl acetate
Barnier,Blanco
, p. 2487 - 2496 (2007/10/03)
Kinetic resolutions by lipase-catalyzed transesterification with 3-iodocyclohex-2-en-1-ol or 3-iodocyclohex-2-en-1-yl acetate followed by inversion of the chirality of the optically active alcohol without separation from the acetate have allowed the preparation of (R)- and (S)-3-iodocyclohex-2-en-1-yl acetate with more than 70% yield and more than 85% ee.
ATOM TRANSFER CYCLIZATION REACTIONS OF α-IODO CARBONYLS
Curran, Dennis P.,Chang, Chi-Thai
, p. 2477 - 2480 (2007/10/02)
The free radical isomerization of unsaturated α-iodo carbonyls to cyclic γ-iodo carbonyls is described.Iodine atom abstraction from the starting iodide by the cyclic radical is the key chain transfer step.
