188635-27-0Relevant academic research and scientific papers
Enzyme- and ruthenium-catalyzed dynamic kinetic resolution of functionalized cyclic allylic alcohols
Lihammar, Richard,Millet, Renaud,Baeckvall, Jan-E.
, p. 12114 - 12120 (2014/01/06)
Enantioselective synthesis of functionalized cyclic allylic alcohols via dynamic kinetic resolution has been developed. Cyclopentadienylruthenium catalysts were used for the racemization, and lipase PS-IM or CALB was employed for the resolution. By optimization of the reaction conditions the formation of the enone byproduct was minimized, making it possible to prepare a range of optically active functionalized allylic alcohols in good yields and high ee's.
Samarium(II) Iodide-Promoted Reactions of 2,3-Epoxycycloalkanone Hydrazones
Kang, Han-Young,Hong, Woo Sang,Lee, Sang Hak,Choi, Kyung Il,Koh, Hun Yeong
, p. 33 - 34 (2007/10/03)
The reaction of hydrazones of 2,3-epoxycycloalkanone promoted by samarium(II) iodide has been investigated to study the behavior of the compounds containing C=N bonds in the presence of this powerful single-electron transfer reagent. For the hydrazones derived from 2,3-epoxycyclopentanone and 2,3-epoxycyclohexanone, 3-iodo-2-cycloalkenols were isolated while the corresponding 2-cycloalkenols were the products when the hydrazones from 2,3-epoxycycloheptanone and 2,3-epoxycyclooctanone were reacted.
