6402-36-4 Usage
Chemical Properties
white to beige crystalline powder
Uses
Traumatic Acid, is the product of a biosynthetic pathway from a physiological role of alpha-ketol fatty acids in plant lipid hydroperoxide lyase metabolism. This compound is also used in would healing as it stimulates cell division to form a protective callus around the wound site.
Definition
ChEBI: A monounsaturated straight-chain dicarboxylic acid with the double bond at C-2; a plant wound-healing hormone.
Purification Methods
Crystallise the acid from EtOH, acetone or glyme. The bis-4-phenylphenacyl ester has m 144-145o (from EtOH). [Beilstein 2 III 1978, 2 IV 2279.]
Check Digit Verification of cas no
The CAS Registry Mumber 6402-36-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,4,0 and 2 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6402-36:
(6*6)+(5*4)+(4*0)+(3*2)+(2*3)+(1*6)=74
74 % 10 = 4
So 6402-36-4 is a valid CAS Registry Number.
InChI:InChI=1/C12H20O4/c13-11(14)9-7-5-3-1-2-4-6-8-10-12(15)16/h7,9H,1-6,8,10H2,(H,13,14)(H,15,16)/p-2
6402-36-4Relevant articles and documents
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English,Bonner,Haagen-Smit
, p. 3436 (1939)
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A supramolecular catalyst for the decarboxylative hydroformylation of α,β-unsaturated carboxylic acids
Smejkal, Tomas,Breit, Bernhard
, p. 3946 - 3949 (2008/12/23)
(Chemical Equation Presented) Head 'em up, move 'em out, aldehyde! A catalytic transformation of α,β-unsaturated carboxylic acids into aldehydes through a hydroformylation-decarboxylation process has been developed (see scheme; Do = donor ligand, FG1 and FG2 = complementary functional groups). The reaction proceeds at mild conditions, tolerates many functional groups, and liberates CO2 as the only stoichiometric by-product.
SYNTHESIS OF TRAUMATOIC (2E-DODECENEDIOIC) ACID FROM DODECANEDIOIC ACID
Zakharkin, L. I.,Guseva, V. V.,Churilova, I. M.
, p. 419 - 421 (2007/10/02)
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