640270-82-2

Basic information

• Product Name: [C6F4(B(C6F5)2)2(μ-Cl][CPh3]
• CAS NO: 640270-82-2
• Molecular Weight: 1116.69
• Mol File: 640270-82-2.mol

Chemical Properties

• CAS DataBase Reference: [C6F4(B(C6F5)2)2(μ-Cl][CPh3](CAS DataBase Reference)
• NIST Chemistry Reference: [C6F4(B(C6F5)2)2(μ-Cl][CPh3](640270-82-2)
• EPA Substance Registry System: [C6F4(B(C6F5)2)2(μ-Cl][CPh3](640270-82-2)

Safety Data

• Hazardous Substances Data: 640270-82-2(Hazardous Substances Data)

Upstream product

• 640270-80-0 [C6F4(B(C6F5)2)2(μ-Cl][CMe2Ph] 
• 76-83-5 trityl chloride 
• 223769-13-9 1,2-C₆F₄(B(C(C₆F₅)2)2 

Relevant articles and documents

Isobutene Polymerization Using a Chelating Diborane Co-Initiator

Lewis acidic diborane 1 (J. Am. Chem. Soc. 1999, 121, 3244?3245) is highly effective for both proton- and cationogen-initiated isobutene polymerization in hydrocarbon media at low temperature. Reactions of diborane 1 with cumyl chloride and cumyl methyl ether were studied by variable-temperature 1H and 19F NMR spectroscopy. At low temperatures stable ion pairs 2a and 2b are formed; at higher temperatures these ion-pairs form phenyl-1,3,3-trimethylindan (3) with concomitant release of HCl to form 1 in the case of 2a or degradation of the anion (2b). Reaction between Ph3C-Cl and diborane 1 resulted in the generation of an ion-pair 4 consisting of the Ph3C cation very weakly associated with the chelated, μ-Cl counteranion as revealed by X-ray crystallography. Copyright