64080-56-4Relevant academic research and scientific papers
Highly selective anti-Markovnikov addition of thiols to vinyl ethers under solvent- and catalyst-free conditions
Lou, Feng-Wen,Xu, Jian-Ming,Liu, Bo-Kai,Wu, Qi,Pan, Qian,Lin, Xian-Fu
, p. 8815 - 8818 (2008/03/18)
A simple and efficient protocol for the anti-Markovnikov addition of thiols to vinyl ethers under solvent- and catalyst-free conditions has been established. A series of thiol ethers containing oxygen atom were obtained with good to excellent yields.
REACTIONS OF THIIRANES. III.* SYNTHESIS AND MASS SPECTRA OF THIOETHYLENE GLYCOL DIETHERS
Rodin, A. A.,Sarkisov, Yu. S.,V'yunov, K. A.,Ginak, A. I.
, p. 1671 - 1676 (2007/10/02)
The synthesis of thioethylene glycol diethers from thiirane with the use of allyl chloride and benzyl chloride as electrophiles is described.It was shown that in the absence of effective electrophiles opening of thiirane by phenols leads to the formation of a polymeric product.The dissociative ionization of compounds containing sulfide and ether groups at the same time is discussed.
