64126-56-3Relevant academic research and scientific papers
Palladium-catalyzed direct arylation of indoles with cyclohexanones
Chen, Shanping,Liao, Yunfeng,Zhao, Feng,Qi, Hongrui,Liu, Saiwen,Deng, Guo-Jun
supporting information, p. 1618 - 1621 (2014/04/17)
A novel palladium catalyzed approach to 3-arylindoles was developed from indoles and cyclohexanones. Various cyclohexanones acted as aryl sources via an alkylation and dehydrogenation sequence using molecular oxygen as the hydrogen acceptor. This method showed good regioselectivity and afforded 3-arylindoles as the sole products.
Palladium-catalyzed intermolecular C3 alkenylation of indoles using oxygen as the oxidant
Chen, Wen-Liang,Gao, Ya-Ru,Mao, Shuai,Zhang, Yan-Lei,Wang, Yu-Fei,Wang, Yong-Qiang
supporting information, p. 5920 - 5923 (2013/02/22)
A general and efficient palladium-catalyzed intermolecular direct C3 alkenylation of indoles using oxygen as the oxidant has been developed. The reaction is of complete regio- and stereoselectivity. All products are E-isomers at the C3-position, and no Z-
Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization
Grimster, Neil P.,Gauntlett, Carolyn,Godfrey, Christopher R. A.,Gaunt, Matthew J.
, p. 3125 - 3129 (2007/10/03)
(Chemical Equation Presented) Either the C2- or the C3-substituted product can be obtained with the same palladium(II) catalyst in an oxidative intermolecular alkenylation of indoles. A variety of conditions can be used for derivatization at the 3-positio
