641618-99-7Relevant academic research and scientific papers
A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones
Bi, Xihe,Sivaguru, Paramasivam,Song, Qingmin,Wang, Zikun,Zanoni, Giuseppe,Zhang, Xiaolong,Zhang, Xinyu
supporting information, (2021/12/23)
Hydrodefluorination is one of the most promising chemical strategies to degrade perfluorochemicals into partially fluorinated compounds. However, controlled progressive hydrodefluorination remains a significant challenge, owing to the decrease in the stre
COMPOSITIONS AND METHODS OF PROMOTING ORGANIC PHOTOCATALYSIS
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Paragraph 0066; 0068; 0216-0218, (2018/09/12)
The invention provides novel compounds and methods that are useful in promoting reactions that proceed through an oxidative quenching pathway. In certain embodiments, the reactions comprise atom transfer radical polymerization.
Silver-catalyzed hydrotrifluoromethylation of unactivated alkenes with CF3SiMe3
Wu, Xinyue,Chu, Lingling,Qing, Feng-Ling
supporting information, p. 2198 - 2202 (2013/03/28)
A silver bullet: The title reaction results in selective formation of trifluoromethylated alkanes, and is in contrast to the previously reported transition-metal-catalyzed trifluoromethylation of olefins to generate a series of trifluoromethylated allylic compounds. Preliminary mechanistic investigations indicate that the current hydrotrifluoromethylation proceeds through a pathway involving a CF3 radical species. Copyright
