64196-49-2Relevant academic research and scientific papers
A simple and effective approach to the via one-pot reactions in water
Hosseini, Abolfazl,Khalilzadeh, Mohammad A.,Hallajian, Sara,Tajbakhsh, Mahmood
experimental part, p. 225 - 232 (2011/04/24)
Chemical Equation Presented Water-accelerated synthesis of organic target molecules has been used as a key method for the preparation of phosphoryloxy phosphonate derivatives. Condensation reactions of acid chlorides with dialkyl (aryl) phosphites in the
Lanthanoid-metal-mediated reaction of acylphosphonates: evidence for the formation of an acyllanthanoid complex
Taniguchi, Yuki,Fujii, Nobuto,Takaki, Ken,Fujiwara, Yuzo
, p. 173 - 180 (2007/10/02)
The reactions of diethyl acylphosphonates (1a-e) with Yb and Sm were examined.Reactivities of Yb to 1a-e are different from those of Li and Na.Typically, ethyl benzoylphosphonate (1a) reacts with Yb metal in tetrahydrofuran-hexamethylphosphoramide to afford diethyl 1,2-diphenyl-2-oxoethyl phosphate (2a) and diethyl 1-(diethyl-phosphoryloxy)-1-phenylmethylphosphonate (3a) The formations of 2a and 3a were explained best by the formation of acylytterbium complexes.Keywords: Ytterbium; Samarium; Acylphosphonate; Phosphorus
Novel Synthetic Aspects of the Phosphonate-Phosphate-Rearrangement. II. Synthesis of Enolphosphates from 1-Oxoalkanphosphonates and Sulfur-Ylides
Hammerschmidt, Friedrich,Zbiral, Erich
, p. 1015 - 1024 (2007/10/02)
Acylphosphonates 1 react with Sulfur-ylides 2 to give enolphosphates 3 and phosphonophosphates 4.The product ratio of 3 and 4 is determined by the substituent R3.If R3 is not electronwithdrawing the phosphonophosphate 4 is the sole reaction product. - Keywords: Acylphosphonates, behaviour towards S-ylides; Rearrangement of α-hydroxyphosphonates
