6422-86-2Relevant articles and documents
Alcoholysis of polyethylene terephthalate to produce dioctyl terephthalate using choline chloride-based deep eutectic solvents as efficient catalysts
Zhou, Lei,Lu, Xingmei,Ju, Zhaoyang,Liu, Bo,Yao, Haoyu,Xu, Junli,Zhou, Qing,Hu, Yufeng,Zhang, Suojiang
, p. 897 - 906 (2019)
Dioctyl terephthalate (DOTP) is a new kind of green and non-toxic plasticizer. The traditional process to prepare DOTP is costly and complicated, thus it is very necessary to find an efficient and environmentally-friendly way to obtain DOTP. In this study, we prepared DOTP from the alcoholysis of polyethylene terephthalate (PET) by using 2-ethyl-1-hexanol (2-EH) as the solvent, and used choline chloride-based deep eutectic solvents (ChCl-based DESs) as the catalysts due to their cheapness, low toxicity and ease of preparation. Under the optimized conditions (ChCl/Zn(Ac)2 1:1, 5 wt%, 180 °C, 60 min, PET:2-EH 1:5 molar ratio), the conversion of PET and the yield of DOTP were 100% and 84.7%, respectively. Furthermore, the possible mechanism was proposed through density functional theory (DFT) calculations and experimental results. It revealed that the hydrogen bonds (H-bonds) formed between 2-EH and DESs played a key role in accelerating the degradation process. Furthermore, the kinetics of the reaction was also investigated, and the results indicated that the alcoholysis of PET is a first-order reaction with an activation energy of 95.05 kJ mol-1. This work confirmed that ChCl-based DESs are favorable for the degradation of PET to prepare DOTP under mild conditions, which can also be used for other polymer degradation strategies.
A Method for Manufacturing Diester-based Composition
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Paragraph 0044-0049, (2021/03/23)
A method for preparing a diesterase-based composition is provided to improve energy usage and economics of a reaction process by maintaining a portion of alcohol re-fed into a reactor before a reaction completion time.
METHOD FOR PREPARING PLASTICZER OF LOW MIGRATION DIOCTYL TEREPHTHALATE
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Paragraph 0055-0074, (2021/09/28)
A method for preparing a plasticzer of low migration di-2-ethylhexyl terephthalate includes, in the esterification reaction between terephthalic acid (PTA) and 2-ethyl-hexanol (2-EH), adding at least one short-chain alcohol and at least one long-chain alcohol to graft-modify di-2-ethylhexyl terephthalate. The reaction temperature is between 30 oC and 225 oC, and the reaction pressure is between 80 mbar and 1033 mbar. The modified di-2-ethylhexyl terephthalate prepared by the method can serve as an environmentally friendly plasticizer and have low migration and good processing characteristics.