642454-41-9

Upstream product

• 913566-14-0 (+)-(1S,2S)-cis-2-(2'-Hydroxyethyl)-cyclopentanol 
• 43119-29-5 (3aS,6aS)-hexahydrocyclopenta[b]furan-2-one 
• 642454-37-3 (1S,2S)-2-(2-trityloxyethyl)cyclopentanol 
• 642454-39-5 (1S,2S)-2-(2-trityloxyethyl)cyclopentyl benzoate 

Downstream Products

• 642454-47-5 (1S,2R)-2-[2-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)ethyl]cyclopentyl benzoate 
• 642454-45-3 (1S,2S)-2-[2-(tert-butyldiphenylsilyloxy)-1-hydroxyethyl]cyclopentyl benzoate 
• 642454-61-3 (1S,2R)-2-[2-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)ethyl]cyclopentanol 
• 642454-63-5 (2S)-2-[2-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)ethyl]cyclopentanone 
• 642454-43-1 (1S,2S)-2-(1,2-dihydroxyethyl)cyclopentyl benzoate 
• 642454-68-0 Benzoic acid (1S,2S)-2-(2-oxo-ethyl)-cyclopentyl ester 

Relevant academic research and scientific papers

New method for synthesizing the intermediates to 5-HETE from yeast-mediated reduction products by employing Baeyer-Villiger oxidation with complete retention of enantiomeric excess.

(R) and (S)-Aldehydes 2, which are intermediates for the synthesis of (5R) and (5S)-HETE, were respectively synthesized from the yeast-mediated reductive products, hydroxy ester 3 and cis-lactone 4, through Baeyer-Villiger oxidation with complete retention of enantiomeric excess.