64262-49-3Relevant academic research and scientific papers
Generation of Homochiral Quaternary Carbon Centres from (Vinylketenimine)tricarbonyliron(0) Complexes
Alcock, Nathaniel W.,Pike, Graham A.,Richards, Christopher J.,Thomas, Susan E.
, p. 531 - 534 (1990)
The first homochiral (vinylketenimine)tricarbonyliron(0) complexes have been formed.Nucleophilic attack occurs exclusively on their exo face and after an oxidative work-up homochiral β,γ-unsaturated carboxylic acids containing an α quaternary carbon centre are obtained.
Nucleophilic Addition to Vinylketenimine Complexes. The Asymmetric Synthesis of Carbon Quaternary Centres
Richards, Christopher J.,Thomas, Susan E.
, p. 143 - 160 (2007/10/02)
Addition of alkyl-lithium reagents to (vinylketenimine)tricarbonyliron(0) complexes generates compounds containing carbon quaternary centres.The major products from these reactions are either amides or aldehydes depending upon the conditions employed.Dias
