Tetrahedron Asymmetry p. 531 - 534 (1990)
Update date:2022-08-03
Topics:
Alcock, Nathaniel W.
Pike, Graham A.
Richards, Christopher J.
Thomas, Susan E.
The first homochiral (vinylketenimine)tricarbonyliron(0) complexes have been formed.Nucleophilic attack occurs exclusively on their exo face and after an oxidative work-up homochiral β,γ-unsaturated carboxylic acids containing an α quaternary carbon centre are obtained.
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