64268-25-3Relevant academic research and scientific papers
Palladium-catalyzed C(sp3)-C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes
Cai, Guilong,Huang, Yingda,Du, Tingting,Zhang, Shaowen,Yao, Bo,Li, Xiaofang
supporting information, p. 5425 - 5427 (2016/05/09)
The first C(sp3)-C(sp2) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.
Synthesis and photochemical properties of stilbenophanes tethered by silyl chains. Control of (2π + 2π) photocycloaddition, cis-trans photoisomerization, and photocyclization
Maeda, Hajime,Nishimura, Ko-Ichi,Mizuno, Kazuhiko,Yamaji, Minoru,Oshima, Juro,Tobita, Seiji
, p. 9693 - 9701 (2007/10/03)
Novel macrocyclic and medium-size stilbenophanes tethered by silyl chains were synthesized, and their photochemical and photophysical properties were examined. Direct photoirradiation of macrocyclic stilbenophanes gave intramolecular photocycloadducts ste
General access to para-substituted styrenes
Langle, Sandrine,David-Quillot, Franck,Balland, Alexia,Abarbri, Mohamed,Duchêne, Alain
, p. 113 - 119 (2007/10/03)
A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.
General access to para-substituted styrenes
Langle, Sandrine,David-Quillot, Franck,Balland, Alexia,Abarbri, Mohamed,Duchêne, Alain
, p. 113 - 119 (2015/03/05)
A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.
A novel synthesis of 4B-element-containing styrene derivatives
Nagasaki, Yukio,Kurosawa, Koichi,Tsuruta, Teiji
, p. 3036 - 3038 (2007/10/02)
To synthesize 4B-group element-containing styrene monomers, alkylmetalation reactions of 4-methylstyrene (1) in the presence of lithium diisopropylamide (2) were investigated. Trialkylsilylation of 1 proceeded easily by the reaction with trialkylsilyl chloride in the presence of 2 to form mono- and bis-trialkylsilylated methylstyrene. This synthetic method was expanded to other 4B-elementcontaining styrenes such as germyl and stannyl compounds.
