64277-86-7

Basic information

• Product Name: Benzoic acid, 4-(1,1-diethylpropyl)-, methyl ester
• CAS NO: 64277-86-7
• Molecular Formula: C15H22O2
• Molecular Weight: 234.338
• Mol File: 64277-86-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(1,1-diethylpropyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(1,1-diethylpropyl)-, methyl ester(64277-86-7)
• EPA Substance Registry System: Benzoic acid, 4-(1,1-diethylpropyl)-, methyl ester(64277-86-7)

Safety Data

• Hazardous Substances Data: 64277-86-7(Hazardous Substances Data)

Upstream product

• 73908-04-0 triethylcarbinyl bromide 
• 619-42-1 4-methoxycarbonylphenyl bromide 

Relevant articles and documents

Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides

A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary centers in moderate to excellent yields with excellent functional group tolerance. Electron-deficient arenes are generally more effective in inhibiting alkyl isomerization. The reactions proceed successfully with pyridine or 4-(dimethylamino)pyridine, while imidazolium salts slightly enhance the coupling efficiency.