64299-47-4Relevant academic research and scientific papers
A general, regiospecific synthetic route to perfluoroalkylated arenes via arenediazonium salts with RFCu(CH3CN) complexes
Jiang, Dong-Fang,Liu, Chao,Guo, Yong,Xiao, Ji-Chang,Chen, Qing-Yun
supporting information, p. 6303 - 6309 (2015/03/30)
A mild method of converting arylamines into perfluoroalkylated arenes is described. Relatively stable RFCu(CH3CN) complexes are used as perfluoroalkylating agents, which react smoothly with arenediazonium salts to produce various perfluoroalkylarenes in good yields. Based on the results of clock trapping experiments with diallyl ether, a radical process might be involved in the reaction.
LIQUID CRYSTALS CONTAINING FLUORINE. IX. 4-CYANOPHENYL 4-(PERFLUOROALKYL)BENZOATES AND TRANS-4-(PERFLUOROALKYL)CYCLOHEXANECARBOXYLATES
Fialkov, Yu. A.,Zalesskaya, I. M.,Yagupol'skii, L. M.
, p. 1781 - 1787 (2007/10/02)
By hydrogenation of 4-(perfluoroalkyl)benzoic esters at platinum and subsequent hydrolysis cis- and trans-4-(perfluoroalkyl)cyclohexanecarboxylic acids were obtained.A convenient method was foun for the isolation of the trans isopmers. 4-Phenyl esters of
