642993-55-3Relevant academic research and scientific papers
Concise epoxide-based synthesis of the C14-C25 bafilomycin A1 polypropionate chain
Valentín, Elizabeth M.,Mulero, Marlenne,Prieto, José A.
, p. 2199 - 2201 (2012/05/19)
An efficient nonaldol convergent synthesis of the C14-C25 polyketide fragment of bafilomycin A1 was completed in 16% overall yield and 8 steps in its longest linear sequence. This synthesis highlights the formation of the key fragments using a
Enantioselective monoreduction of 2-alkyl 1,3-diketones using chiral ruthenium catalysts. Synthesis of the C14-C25 fragment of bafilomycin A 1
Eustache, Florence,Dalko, Peter I.,Cossy, Janine
, p. 8823 - 8826 (2007/10/03)
The enantioselective monoreduction of 2-alkyl 1,3-diketones by dynamic kinetic resolution using optically active ruthenium catalysts allowed the preparation of the C14-C25 fragment of bafilomycin A1.
