64357-42-2Relevant articles and documents
Negishi alkyl-aryl cross-coupling catalyzed by Rh: Efficiency of novel tripodal 3-diphenylphosphino-2-(diphenylphosphino)methyl-2-methylpropyl acetate ligand
Ejiri, Syogo,Odo, Shunsuke,Takahashi, Hideki,Nishimura, Yugo,Gotoh, Kazuma,Nishihara, Yasushi,Takagi, Kentaro
supporting information; experimental part, p. 1692 - 1695 (2010/09/03)
3-Diphenylphosphino-2-(diphenylphoshino)methyl-2-methylpropyl acetate acted as an efficient ligand for a Rh catalyst, achieving cross-coupling between arylzinc compounds bearing electron-withdrawing groups and alkyl electrophiles. The beneficial effect of the tripodal ligand and such aryl nucleophiles was discussed with regard to the specificity of the Rh catalysis.