64357-67-1Relevant articles and documents
Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites
Ramamurthy, V.,Corbin, D. R.,Eaton, D. F.
, p. 5269 - 5278 (2007/10/02)
The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated.Product distributions varied significantly from that observed in benzene.In addition, it differed between various alkali-metal cation-exchanged samples.These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule.Although this study is restricted to ketones, the knowledge gained is expected to be of general value.
Modification of Photochemical Reactivity by Zeolites: Selective Photorearrangement of α-Alkyldeoxybenzoins to p-Alkylbenzophenones in the Cavities of Faujasites
Corbin, D. R.,Eaton, D. F.,Ramamurthy, V.
, p. 5384 - 5386 (2007/10/02)
Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type I α-cleavage process.Such a striking behavior contrasts their normal reactivity in solution.