64358-10-7Relevant academic research and scientific papers
Insertion of arynes into carbon-halogen σ-bonds: Regioselective acylation of aromatic rings
Yoshida, Hiroto,Mimura, Yasuhiro,Ohshita, Joji,Kunai, Atsutaka
, p. 2405 - 2407 (2008/02/08)
Arynes were found to insert into carbon-halogen σ-bonds of various acid halides, enabling acyl and halogen moieties to be introduced simultaneously into adjacent positions of aromatic rings. The Royal Society of Chemistry.
The Mechanism of Fries Rearrangement and Acylation Reaction in Polyphosphoric Acid
Sharghi, Hashem,Eshghi, Hossien
, p. 135 - 139 (2007/10/02)
Acylation reaction of m-cresol with 2-chlorobenzoic acid in PPA occurred through a prior esterification, followed by a Fries rearrangement of ester (3) to give benzophenones 4-7.Ester 3 undergoes the Fries rearrangement in PPA, giving benzophenones 4-7 in
