64358-63-0Relevant academic research and scientific papers
Selective synthesis of monohydrosilanes by the reactions of organoytterbium iodides with dihydrosilanes
Jin, Wu-Song,Makioka, Yoshikazu,Kitamura, Tsugio,Fujiwara, Yuzo
, p. 955 - 956 (2007/10/03)
Monohydrosilanes can be prepared selectively in high yields from the reaction of various aryl and alkyl iodides with ytterbium metal followed by the reaction with dihydrosilanes.
Sila-Pharmaca, 36. - Sila-Procyclidine: A New Synthesis as well as Investigations of the Peripheral and Central Anticholinergic Activity
Tacke, Reinhold,Pikies, Jerzy,Linoh, Haryanto,Rohr-Aehle, Regine,Goenne, Sigrid
, p. 51 - 58 (2007/10/02)
Starting with Cl3SiCH2Cl, sila-procyclidine (1b) as well as its derivatives 2b (sila-trihexyphenidyl), 3b, and 4b (sila-cycrimine) were prepared by a new six-step synthesis with a total yields of 16 (1b), 19 (2b), 8 (3b) and 7percent (4b), respectively. -
ASYMMETRIC INDUCTION BY CHIRAL SILICON GROUPS
Larson, Gerald L.,Torres, Evelyn
, p. 19 - 28 (2007/10/02)
The reduction of racemic RPhMeSiCCl2CH3 systems (R=cyclohexyl, isoprpyl, t-butyl and 2-mesityl) to the diastereomeric RPhMeSiCHClCH3 with tributyltin hydride was used as a probe into the potential of the RPhMeSi group to induce asymmetry at an α position.Favorable results were obtained for R=mesityl.
