64358-63-0Relevant articles and documents
Selective synthesis of monohydrosilanes by the reactions of organoytterbium iodides with dihydrosilanes
Jin, Wu-Song,Makioka, Yoshikazu,Kitamura, Tsugio,Fujiwara, Yuzo
, p. 955 - 956 (2007/10/03)
Monohydrosilanes can be prepared selectively in high yields from the reaction of various aryl and alkyl iodides with ytterbium metal followed by the reaction with dihydrosilanes.
ASYMMETRIC INDUCTION BY CHIRAL SILICON GROUPS
Larson, Gerald L.,Torres, Evelyn
, p. 19 - 28 (2007/10/02)
The reduction of racemic RPhMeSiCCl2CH3 systems (R=cyclohexyl, isoprpyl, t-butyl and 2-mesityl) to the diastereomeric RPhMeSiCHClCH3 with tributyltin hydride was used as a probe into the potential of the RPhMeSi group to induce asymmetry at an α position.Favorable results were obtained for R=mesityl.
