64389-72-6Relevant academic research and scientific papers
Process for preparing hydrocarbyl and silahydrocarbyl transition metal dihydrocarbylamides
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, (2008/06/13)
A poly(dihydrocarbylamide) of a transition metal of groups IV, V or VI is reacted with a hydrocarbyllithium or a silahydrocarbyllithium in a solvent and a hydrocarbyl- or silahydrocarbyl(transition metal) dihydrocarbylamide is recovered. Exemplary is the process of dissolving vanadium tetrakis(dimethylamide) in pentane and adding trimethylsilylmethyllithium to obtain bis (trimethylsilylmethyl)vanadium bis(dimethylamide).
